The novel technique of low-temperature scanning tunneling microscopy i
s used to study conventional and high-T(c) superconductors (spatial id
entification and distribution of the superconducting gap, vortex movem
ent, etc.), but also custom-designed materials which are unstable at r
oom temperature, e.g. xenon layers and size-selected clusters, or spec
ies whose rotational or vibrational movements have to be frozen in to
achieve atomic resolution. We present the specific design and advantag
es of our low-temperature ultra-high vacuum scanning tunneling microsc
ope along with recent results on the internal structure of C60 fullere
ne molecules and their photon emitting properties.