LOCAL STRUCTURES AROUND PB(II) AND SN(II) IN CH(3)NH(3)PBX(3) (X=CL, BR, I) AND CH(3)NH(3)SNX(3) (X=BR, I) STUDIED BY PB L(III)-EDGE AND SNK-EDGE EXAFS

Authors
ISHIDA H MAEDA H HIRANO A KUBOZONO Y FURUKAWA Y
Citation
H. Ishida et al., LOCAL STRUCTURES AROUND PB(II) AND SN(II) IN CH(3)NH(3)PBX(3) (X=CL, BR, I) AND CH(3)NH(3)SNX(3) (X=BR, I) STUDIED BY PB L(III)-EDGE AND SNK-EDGE EXAFS, Physica status solidi. a, Applied research, 159(2), 1997, pp. 277-282
Citations number
19
Categorie Soggetti
Physics, Condensed Matter
Journal title
Physica status solidi. a, Applied research → ACNP
ISSN journal
00318965
Volume
159
Issue
2
Year of publication
1997
Pages
277 - 282
Database
ISI
SICI code
0031-8965(1997)159:2<277:LSAPAS>2.0.ZU;2-L
Abstract
Local structures around Pb(II) and Sn(II) in CH(3)NH(3)PbX(3) (X=Cl, B r, I) and CH(3)NH(3)SnX(3) (X=Br, I) were studied by Pb L(III)-edge an d Sn K-edge EXAFS in the temperature range of 10 to 293 K. The M-X dis tances (M=Pb, Sn; X=Cl, Br, I), the coordination numbers, and the Deby e-Waller factors were determined in three, four, three, five, and two solid phases of CH3NH3PbCl3, CH3NH3PbBr3, CH3NH3PbI3, CH3NH3SnBr3, and CH3NH3SnI3, respectively. Five kinds of deformed octahedra consisting of halogens were observed.