PRODUCT BRANCHING RATIOS OF THE NH((3)SIGMA(-))-))+NO2 REACTIONS(NO AND NH((3)SIGMA()

Authors
QUANDT RW HERSHBERGER JF
Citation
Rw. Quandt et Jf. Hershberger, PRODUCT BRANCHING RATIOS OF THE NH((3)SIGMA(-))-))+NO2 REACTIONS(NO AND NH((3)SIGMA(), Journal of physical chemistry, 99(46), 1995, pp. 16939-16944
Citations number
45
Categorie Soggetti
Chemistry Physical
Journal title
Journal of physical chemistry → ACNP
ISSN journal
00223654
Volume
99
Issue
46
Year of publication
1995
Pages
16939 - 16944
Database
ISI
SICI code
0022-3654(1995)99:46<16939:PBROTN>2.0.ZU;2-R
Abstract
The title reactions were studied at 298 K using time-resolved infrared diode laser spectroscopy. For the NH ((3) Sigma(-)) + NO reaction, N2 O + H were found to be the primary products, with a branching ratio of 0.77 +/- 0.08, in good agreement with other recent measurements. For the NH ((3) Sigma(-)) + NO2 reaction, the measured branching ratio was 0.41 +/- 0.15 into the N2O + OH channel and 0.59 +/- 0.15 into the NO + HNO channel.