KINETIC-STUDY OF THE REACTION OF LAURIL ALCOHOL WITH H2S

Authors
MASHKIN VY CHERNOMYRDINA NA MASHKINA AV
Citation
Vy. Mashkin et al., KINETIC-STUDY OF THE REACTION OF LAURIL ALCOHOL WITH H2S, Kinetics and catalysis, 36(5), 1995, pp. 639-643
Citations number
8
Categorie Soggetti
Chemistry Physical
Journal title
Kinetics and catalysis → ACNP
ISSN journal
00231584
Volume
36
Issue
5
Year of publication
1995
Pages
639 - 643
Database
ISI
SICI code
0023-1584(1995)36:5<639:KOTROL>2.0.ZU;2-3
Abstract
The kinetics of the heterogeneous catalytic reaction of lauril alcohol and H2S on aluminum oxide modified with alkali at 275 - 360 degrees C is studied. The reaction predominantly proceeds via the consecutive s cheme: the reaction of lauril alcohol with H2S results in n-dodecaneth iol, which then partially decomposes with the formation of dodecene an d H2(S). A kinetic equation based on the postulated reaction mechanism is obtained; the equation describes the process on the nonuniform cat alyst surface.