The compounds of a hydrotalcite structure formed from copper-zinc-chro
mium hydroxycarbonate at an increasing temperature of calcination are
studied. At temperatures ranging from 300 to 350 degrees C, the decomp
osition of-hydroxycarbonate occurs to yield anion-modified oxides in w
hich chromium cations are partially present in the degree of oxidation
+6. The structure of the anion-modified oxide is governed by the natu
re of a bivalent cation and differs from that of spinel. The formation
of the spinel structure in the copper-chromium system is observed at
temperatures above 450 degrees C. The distribution of cations over the
ir crystallographic positions in the copper-zinc-chromium spinels depe
nds on the Cu :Zn ratio and calcination temperature.