PULSED FIELD THRESHOLD IONIZATION OF VAN-DER-WAALS COMPLEXES - THE DISSOCIATION-ENERGY OF IONIC AND NEUTRAL DIBENZO-P-DIOXIN-CENTER-DOT-AR AND CENTER-DOT-KR-84

Authors
GREBNER TL NEUSSER HJ
Citation
Tl. Grebner et Hj. Neusser, PULSED FIELD THRESHOLD IONIZATION OF VAN-DER-WAALS COMPLEXES - THE DISSOCIATION-ENERGY OF IONIC AND NEUTRAL DIBENZO-P-DIOXIN-CENTER-DOT-AR AND CENTER-DOT-KR-84, Chemical physics letters, 245(6), 1995, pp. 578-584
Citations number
32
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
Chemical physics letters → ACNP
ISSN journal
00092614
Volume
245
Issue
6
Year of publication
1995
Pages
578 - 584
Database
ISI
SICI code
0009-2614(1995)245:6<578:PFTIOV>2.0.ZU;2-M
Abstract
The technique of mass selective pulsed field threshold ionization of h igh long-lived Rydberg states has been applied to dibenzo-p-dioxin (DD ), DD . Ar, and DD-Kr-84 yielding adiabatic ionization energies of 612 83, 61071, and 61005 cm(-1) respectively. A sharp energetic threshold for the disappearance of the parent threshold ion signal of (DD . Ar)( +) and the appearance of the daughter threshold ion signal is observed . This leads to accurate values of the dissociation energy E(0) = 717 cm(-1) in (DD . Ar)(+), E(0) = 918 cm(-1) in (DD .Kr-84)(+) and to D-0 = 505 cm(-1) in DD . Ar, D-0 = 640 cm(-1) in DD .Kr-84.