H. Grimech et A. Khater, MEAN SURFACE PHONON-DISPERSION CURVES FOR LOW-INDEX FCC (A(C)B(1-C))(1) B(KLM) SURFACE ALLOYS/, Surface science, 341(3), 1995, pp. 227-240
A theoretical formalism for calculating the mean surface phonon disper
sion curves for surface alloy systems (A(c)B(1-c))(1)/B(klm) is develo
ped, using the matching method and an effective field approach. Numeri
cal results which are presented for the (100), (110), and (111) surfac
es of the (PtcCu1-c)(1)/Cu(klm) system are, however, carried out withi
n the virtual crystal approximation which is described by random distr
ibutions of Pt atoms. In this approximation short range disorder effec
ts are not predicted. Significant shifts of surface dispersion branche
s are found, as functions of the defect concentration c (0 less than o
r equal to c less than or equal to 1), that would be measurable within
instrumental resolution of EELS and HAS. Thus, the fit of the calcula
ted branches to the experimental data, in particular for small wavevec
tors, would lead to information concerning the values of the defect cr
ystal interaction parameters.