HYDROTHERMAL SYNTHESIS AND CHARACTERIZATION OF 2- AND 3-DIMENSIONAL SOLIDS OF THE OXOVANADIUM(IV)-PHOSPHITE SYSTEM - THE STRUCTURES OF N(ME)(CH2CH2)(2)N(ME)H]-[(VO)(4)(OH)(2)(HPO3)(4)], [H2N(CH2CH2)(2)NH2][(VO)(3)(HPO3)(4)(H2O)(2)], AND [VO(HPO3)(H2O)]

Authors
BONAVIA G DEBORD J HAUSHALTER RC ROSE D ZUBIETA J
Citation
G. Bonavia et al., HYDROTHERMAL SYNTHESIS AND CHARACTERIZATION OF 2- AND 3-DIMENSIONAL SOLIDS OF THE OXOVANADIUM(IV)-PHOSPHITE SYSTEM - THE STRUCTURES OF N(ME)(CH2CH2)(2)N(ME)H]-[(VO)(4)(OH)(2)(HPO3)(4)], [H2N(CH2CH2)(2)NH2][(VO)(3)(HPO3)(4)(H2O)(2)], AND [VO(HPO3)(H2O)], Chemistry of materials, 7(11), 1995, pp. 1995
Citations number
27
Categorie Soggetti
Chemistry Physical","Material Science
Journal title
Chemistry of materials → ACNP
ISSN journal
08974756
Volume
7
Issue
11
Year of publication
1995
Database
ISI
SICI code
0897-4756(1995)7:11<1995:HSACO2>2.0.ZU;2-W
Abstract
The hydrothermal reactions of VCl4 with phosphorous acid H3PO3, in the presence of the appropriate organoamine, yield new examples of the ox ovanadium(IV)-phosphite class of materials, [HN(Me)(CH2CH2)(2)N(Me)H] [(VO)(4)(OH)(2)(HPO3)(4)] (1), [H2N(CH2CH2)(2)NH2] [(VO)(3)(HPO3)(4)(H 2O)(2)] (2), and [VO(HPO3)(H2O)] (3). The 3-D framework structure adop ted by 3 is illustrated.