Y. Namikawa et al., EFFECTS OF MELT CONVECTION ON YBA2CU3O7-X SINGLE-CRYSTAL GROWTH BY PULLING METHOD, Nippon Kinzoku Gakkaishi, 59(10), 1995, pp. 1047-1054
The melt convection phenomena in YBa2Cu3O7-x, (YBCO) single crystal gr
owth by the modified pulling method (Solute Rich Liquid-Crystal Pullin
g method; SRL-CP method) have been investigated by using a numerical c
alculation. The finite difference method was used to calculate the ste
ady state of the axisymmetric 2-dimensional incompressible viscous flu
id system. In order to clarify the property of the melt convection, th
e dimensional analysis was performed with changing various parameters
for the calculation, such as the crystal rotation rate, the melt visco
sity, etc. The intensity ratio of the forced to the natural convection
in the melt could be expressed by Re(1.5)Dsc(0.7)/Gr, where Re, Gr an
d Dsc were the Renolds number, the Grashof number and the diameter rat
io of the crystal to the crucible, respectively. And also, the dimensi
onless crystal growth interface temperature, Theta could be expressed
by Theta=C Re(0.028)Pr(0.041)Gr(0.019)Dsc(0.064), where Pr was the Pra
ndtl number and C was a constant. These results agreed well with the e
xperimental results, and indicated that in this system, the heat trans
port was mainly dominated by the forced convection. On the basis of th
ese calculated results, the YBCO single crystal which was 14.5 mm x 14
.5 mm x 13 mm could be grown along the c-axis by the pulling method.