ULTRAFINE MAGHEMITE PARTICLES .2. THE SPIN-CANTING EFFECT REVISITED

The magnetic structure of ultrafine maghemite particles was studied by Mossbauer spectroscopy. We have compared the degree of spin alignment obtained in applied magnetic fields in particulate samples with diffe rent frozen-in orientational distributions of the easy directions of t he magnetization. Full alignment of the spins was not obtained even in large applied fields (4.35 T). The degree of alignment with the appli ed field was found to be independent of the orientation of the easy di rections in the sample when the applied field was larger than 0.75 T. This result shows that the incomplete alignment of the spins in ultraf ine maghemite particles subjected to large applied fields is not due t o incomplete alignment of the net particle magnetization due to large magnetic anisotropy, but rather stems from a canting of individual spi ns.