Ways, benefits and limitations of extracting the form and size of sing
le latex particles or particle size distributions out of the surface t
opography of non-coalesced latex films obtained by atomic force micros
copy (AFM) are discussed. The general ways to generate the desired inf
ormation out of topographical information in terms of height, surface
curvature and lateral extensions are shown for idealized particles and
measurement conditions. The different sources of information are eval
uated for practical use and the analysis of particle size distribution
s is demonstrated by practical examples. The information content in la
teral particle dimensions is shown to be the most advantageous for pra
ctical use. Determination of latex particle size distributions by AFM
is shown to be an interesting alternative to the arsenal of available
methods with respect to exactness of results, time consummation and in
strumentation costs.