ENDOR STUDY OF MACRORADICALS IN IRRADIATE D POLYETHYLENE

Authors
TOMASHEVSKII EE KVACHADZE NG
Citation
Ee. Tomashevskii et Ng. Kvachadze, ENDOR STUDY OF MACRORADICALS IN IRRADIATE D POLYETHYLENE, Vysokomolekularnye soedinenia. Seria A, 37(10), 1995, pp. 1788-1792
Citations number
16
Categorie Soggetti
Polymer Sciences
Journal title
Vysokomolekularnye soedinenia. Seria A → ACNP
ISSN journal
05075475
Volume
37
Issue
10
Year of publication
1995
Pages
1788 - 1792
Database
ISI
SICI code
0507-5475(1995)37:10<1788:ESOMII>2.0.ZU;2-I
Abstract
ENDOR spectra of free radicals in irradiated polyethylene were measure d in the temperature range +20- -170 degrees C. The constants of hyper fine interaction between unpaired electron and various protons in the macroradical -CH2-CH2-CH2-CH-CH2-CH2-CH2- were determined, and the con formation of radicals was established. The angular misorientation of r adicals with respect to the axis of polymer drawing was evaluated.