L. Melluso et al., CONSTRAINTS ON THE MANTLE SOURCES OF THE DECCAN-TRAPS FROM THE PETROLOGY AND GEOCHEMISTRY OF THE BASALTS OF GUJARAT STATE (WESTERN INDIA), Journal of Petrology, 36(5), 1995, pp. 1393-1432
The bate Cretaceous-early Tertiary flood basalts in the Gujarat area o
f the northwestern Deccan Traps (Kathiawar peninsula, Pavagadh hills a
nd Rajpipla) exhibit a wide range of compositions, from picrite basalt
s to rhyolites; moreover, the basaltic rocks have clearly distinct TiO
2 contents at any given degree of differentiation and strongly resembl
e the low-titanium and high-titanium basalts found in most of the Gond
wana continental flood basalt (CFB) suites Four magma groups are petro
logically and geochemically distinguished: (1) A low-Ti group, charact
erized by rocks with varying SiO2 saturation, and with TiO2 <1.8 wt %,
extremely low incompatible trace element abundances, low Zr/Y (av. 3.
8), Ti/V (av. 27), and a very slight large ion lithophile element (LIL
E) enrichment over high field strength elements (HFSE). These rocks sh
are some features with the Bushe Formation of the Western Ghats farthe
r south, but have distinct geochemical characters, in particular the s
trong depletion in most incompatible trace elements. (2) A high-Ti gro
up, characterized by a more K-rich character than the low-Ti rocks, an
d with a strong enrichment in incompatible elements, similar to averag
e ocean island basalt (OIB), e.g. high TiO2 (>1.8 wt % in picrites), N
b (>19 p.p.m.) (av. 6.5) and Ti/V (au. 47). (3) An intermediate-Ti gro
up, with TiO2 contents slightly lower than the high-Ti rocks at the sa
me degree of evolution, and with correspondingly lower incompatible tr
ace element contents and ratios, in particular K2O, Nb, Ba and Zr/Y (a
v. 5.2). (4) A potassium-rich group (KT), broadly similar in geochemic
al character to the high-Ti group but showing more extreme K, Rb and B
a enrichment (au. K2O/Na2O similar to 1; Ba/Y similar to 20). The most
primitive low-Ti and high-Ti picrites, when corrected for low-pressur
e olivine fractionation, show distinct major (and trace) element geoch
emistry, in particular for CaO/Al2O3, CaO/TiO2 and Al2O3/TiO2, and mod
erate but significant variations in their SiO2 and Fe2O3t contents; th
ese characteristics strongly suggest the involvement of different mant
le sources more depleted for the low-Ti picrites, and richer in cpx fo
r the high-Ti picrites, but with broadly the same pressures of equilib
ration (27-14 kbar). This, in turn, suggests a strong lateral heteroge
neity in the Gujarat Trap mantle. Low-Ti picrites and related differen
tiates in Kathiawar are reported systematically for the first time her
e, and suggest the existence of HFSE-depleted mantle in the northweste
rn Deccan Traps, with extension at least to the Seychelles Islands and
to the area of the Bushe Formation near Bombay in the pre-drift posit
ion, before the development of the Carlsberg Ridge. The absence of cor
relations between LILE/HFSE ratios and SiO2 argues against crustal con
tamination processes acting on the low-Ti picrites, possibly owing to
their probably rapid uprise to the surface. Consequently, the mantle r
egion of this rock group was probably re-enriched by small amounts of
LILE-rich materials. The substantially higher trace element enrichment
of the least differentiated high-Ti picrites, relative to the basalts
of the Ambenali and Mahableshwar Formations of the Western Ghats, tes
tifies also to the presence of more incompatible element rich, GIB-lik
e mantle sources in northern and northwestern Gujarat. These sources w
ere geochemically similar to the present-day Reunion mantle sources.