SYNTHESES OF POLY (BETA-CHLOROETHYL GLYCI DYLETHER) AND KINETIC OF ITS ESTERIFICATION

Authors
HUANG JX ZHU DH LU G WANG ZJ
Citation
Jx. Huang et al., SYNTHESES OF POLY (BETA-CHLOROETHYL GLYCI DYLETHER) AND KINETIC OF ITS ESTERIFICATION, Huaxue xuebao, 53(10), 1995, pp. 1018-1023
Citations number
4
Categorie Soggetti
Chemistry
Journal title
Huaxue xuebao → ACNP
ISSN journal
05677351
Volume
53
Issue
10
Year of publication
1995
Pages
1018 - 1023
Database
ISI
SICI code
0567-7351(1995)53:10<1018:SOP(GD>2.0.ZU;2-F
Abstract
beta-chloroethyl glycidyl ether and its polymer poly (beta-chloroethyl glycidyl ether) have been synthesised, The results show that AlEt(3)- 0.5 H2O system is a effective polymerization initiator for beta-chloro ethyl glycidyl ether. Moreover, the kinetic of esterification of the p oly (beta-chloroethyl glycidyl ether) was studied, and the calculation formula of esterification degree by H-1 NMR and IR spectroscopy was e stablished. Finaly, with the aid of kinetic investigation of photocros slinking the esterificated polymer with a 85% of cinnamate which a hig hest photosensibility of the material was found.