VAPOR-LIQUID-EQUILIBRIUM OF BINARY-MIXTURES OF LIMONENE WITH ALPHA-PINENE AND BETA-PINENE AT REDUCED PRESSURES

Citation
Mf. Rodrigues et Mg. Bernardogil, VAPOR-LIQUID-EQUILIBRIUM OF BINARY-MIXTURES OF LIMONENE WITH ALPHA-PINENE AND BETA-PINENE AT REDUCED PRESSURES, Journal of chemical and engineering data, 40(6), 1995, pp. 1193-1195
Citations number
16
Categorie Soggetti
Engineering, Chemical",Chemistry
ISSN journal
00219568
Volume
40
Issue
6
Year of publication
1995
Pages
1193 - 1195
Database
ISI
SICI code
0021-9568(1995)40:6<1193:VOBOLW>2.0.ZU;2-6
Abstract
Vapor-liquid equilibrium data for the binary systems alpha-pinene + (S )-(-)-limonene and beta-pinene + (S)-(-)-limonene were determined at 5 3.3 and 80.0 kPa in a modified miniature Othmer still. Parameters of t he Wilson, NRTL, and UNIQUAC equations were calculated with the aid of a Nelder-Mead technique to minimize an objective function based on th e total pressure. The results were compared with the predictions of th e UNIFAC method.