Mf. Rodrigues et Mg. Bernardogil, VAPOR-LIQUID-EQUILIBRIUM OF BINARY-MIXTURES OF LIMONENE WITH ALPHA-PINENE AND BETA-PINENE AT REDUCED PRESSURES, Journal of chemical and engineering data, 40(6), 1995, pp. 1193-1195
Vapor-liquid equilibrium data for the binary systems alpha-pinene + (S
)-(-)-limonene and beta-pinene + (S)-(-)-limonene were determined at 5
3.3 and 80.0 kPa in a modified miniature Othmer still. Parameters of t
he Wilson, NRTL, and UNIQUAC equations were calculated with the aid of
a Nelder-Mead technique to minimize an objective function based on th
e total pressure. The results were compared with the predictions of th
e UNIFAC method.