THERMOCHEMISTRY OF VANADIUM(5-SOLUTIONS() IN AQUEOUS)

Authors
LARSON JW
Citation
Jw. Larson, THERMOCHEMISTRY OF VANADIUM(5-SOLUTIONS() IN AQUEOUS), Journal of chemical and engineering data, 40(6), 1995, pp. 1276-1280
Citations number
11
Categorie Soggetti
Engineering, Chemical",Chemistry
Journal title
Journal of chemical and engineering data → ACNP
ISSN journal
00219568
Volume
40
Issue
6
Year of publication
1995
Pages
1276 - 1280
Database
ISI
SICI code
0021-9568(1995)40:6<1276:TOVIA>2.0.ZU;2-G
Abstract
V-51 NMR studies on the chemical equilibria of vanadium(5+) species we re made for aqueous solutions of low ionic strength and pH values rang ing from 2.0 to 12.0. The average charge per V atom of these ionic spe cies is from +1 to -2, and the measurements were made at temperatures of 0, 25, and 50 degrees C. Analysis of these results gave accurate th ermochemical values for the following major constituent ions of these solutions: VO2+, H2VO4-, HVO42-, H2V2O72-, HV2O73-, V2O74-, V4O124-, a nd HV10O285-.