UNSATURATED CYCLIC SULFITES .1. SYNTHESIS AND CONDENSATION WITH TERMINAL ACETYLENE

Authors
KOCHEV DM MYAGKOVA GI
Citation
Dm. Kochev et Gi. Myagkova, UNSATURATED CYCLIC SULFITES .1. SYNTHESIS AND CONDENSATION WITH TERMINAL ACETYLENE, Bioorganiceskaa himia, 21(10), 1995, pp. 806-808
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Bioorganiceskaa himia → ACNP
ISSN journal
01323423
Volume
21
Issue
10
Year of publication
1995
Pages
806 - 808
Database
ISI
SICI code
0132-3423(1995)21:10<806:UCS.SA>2.0.ZU;2-Y
Abstract
Cyclic unsaturated sulfite Delta(5)-1,3-dioxa-2-thialepin-2-oxide synt hesized from (Z)-2-butene-1,4-diol was studied in the condensation wit h 1-heptyne. The direction of the reaction strongly depends on the con ditions. The reaction resulted in (Z)/(E)-2-undecene-5-yn-1-ol and a b y-product, 3-(hydroxymethyl)-1-decene-4-yne.