SYNTHESIS AND X-RAY STRUCTURE OF DIISOPROPYLPHOSPHORYL ALKANEDIYL DIISOTHIOUREA

Authors
LIN WO GARCIA GB SACHETT CMM ALT HG MILIUS W
Citation
Wo. Lin et al., SYNTHESIS AND X-RAY STRUCTURE OF DIISOPROPYLPHOSPHORYL ALKANEDIYL DIISOTHIOUREA, Phosphorus, sulfur and silicon and the related elements, 85(1-4), 1993, pp. 113-118
Citations number
7
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Phosphorus, sulfur and silicon and the related elements → ACNP
ISSN journal
10426507
Volume
85
Issue
1-4
Year of publication
1993
Pages
113 - 118
Database
ISI
SICI code
1042-6507(1993)85:1-4<113:SAXSOD>2.0.ZU;2-B
Abstract
Symmetric organic compounds containing I-phosphoryl-3-imino groups wer e prepared by a two phase reaction between the corresponding dialkylph osphite and alkanediyl diisothiourea. The X-ray structure analysis sho wed that the diisopropylphosphoryl ethylenediisothiourea IIa crystalli zed in the orthorhombic space group Pbca with the cell dimensions a = 16.660(3) angstrom, b = 8.910(2) angstrom, c = 17.457(3) angstrom, z = 4, at -100-degrees-C. The coordination around the phosphorus atom in the molecule is distorted tetrahedrally. The molecule has moieties sli ghtly out of plane around O=P-N-C-N with strong intermolecular hydroge n bonds.