STUDY OF THE REACTIVITY OF NITRILES TOWAR DS DIAZOMETHANE - SYNTHESISAND STRUCTURAL STUDY OF N-METHYL-V-TRIAZOLES

Authors
DANOUN S BAZIARDMOUYSSET G STIGLIANI JL COMMENGES G CARPY A PAYARD M
Citation
S. Danoun et al., STUDY OF THE REACTIVITY OF NITRILES TOWAR DS DIAZOMETHANE - SYNTHESISAND STRUCTURAL STUDY OF N-METHYL-V-TRIAZOLES, Bulletin de la Societe chimique de France, 132(9), 1995, pp. 943-951
Citations number
33
Categorie Soggetti
Chemistry Inorganic & Nuclear",Biology,Chemistry
Journal title
Bulletin de la Societe chimique de France → ACNP
ISSN journal
00378968
Volume
132
Issue
9
Year of publication
1995
Pages
943 - 951
Database
ISI
SICI code
0037-8968(1995)132:9<943:SOTRON>2.0.ZU;2-1
Abstract
In this work, we examined the effect of diazomethane on 12 nitriles. F ive gave rise to three isomeric N-methyl-upsilon-triazoles, which were isolated. Their structural features were established and, in one case , corroborated by X-ray analysis. A generalization of the structural a ttribution by C-13 NMR is proposed. A study of the electronic distribu tion was carried out for a total of 17 nitriles and helped establish a predictive criterion of their reactivity towards diazomethane.