SYNTHESIS AND CRYSTAL-STRUCTURE OF METHYL AMMONIUM POLYVANADATE CH3NH3VO3

Authors
AVERBUCHPOUCHOT MT DURIF A
Citation
Mt. Averbuchpouchot et A. Durif, SYNTHESIS AND CRYSTAL-STRUCTURE OF METHYL AMMONIUM POLYVANADATE CH3NH3VO3, Comptes rendus de l'Academie des sciences. Serie 2, Mecanique, physique, chimie, sciences de l'univers, sciences de la terre, 318(8), 1994, pp. 1067-1072
Citations number
4
Categorie Soggetti
Multidisciplinary Sciences
Journal title
Comptes rendus de l'Academie des sciences. Serie 2, Mecanique, physique, chimie, sciences de l'univers, sciences de la terre → ACNP
ISSN journal
07644450
Volume
318
Issue
8
Year of publication
1994
Part
1
Pages
1067 - 1072
Database
ISI
SICI code
0764-4450(1994)318:8<1067:SACOMA>2.0.ZU;2-W
Abstract
CH3NH3VO3 is orthorhombic, P n a 2(1), with Z = 16 and the following u nit-cell dimensions: a = 11.898 (2), b = 18.641 (2), c = 8.468 (3) ang strom Crystal structure of this new salt is mainly characterized by a layer organization built by planes of infinite (VO3)n, chains alternat ing with planes of methylammonium groups. The structure was performed by using 3,072 reflections with a final R value of 0.028. The complete hydrogen-bond scheme is described.