ELECTROOXIDATIVE FISSION OF CARBON-CARBON DOUBLE-BOND IN A K2OSO2(OH)(4) HIO4 DOUBLE MEDIATORY SYSTEM/

Authors
TANAKA H KIKUCHI R BABA M TORII S
Citation
H. Tanaka et al., ELECTROOXIDATIVE FISSION OF CARBON-CARBON DOUBLE-BOND IN A K2OSO2(OH)(4) HIO4 DOUBLE MEDIATORY SYSTEM/, Bulletin of the Chemical Society of Japan, 68(10), 1995, pp. 2989-2992
Citations number
18
Categorie Soggetti
Chemistry
Journal title
Bulletin of the Chemical Society of Japan → ACNP
ISSN journal
00092673
Volume
68
Issue
10
Year of publication
1995
Pages
2989 - 2992
Database
ISI
SICI code
0009-2673(1995)68:10<2989:EFOCDI>2.0.ZU;2-K
Abstract
Electrooxidation of olefins in the presence of potassium osmate (0.04 molar amount) and periodic acid (0.5 molar amount) afforded the corres ponding carbon-carbon double bond cleavage products in moderate to goo d yields, where the turnover number of periodic acid reached ca. 3.