UNUSUAL 6-COORDINATED AND 8-COORDINATED CADMIUM(II) MALONATE COMPLEX - RELEVANCE TO CD-113 NMR PROBE OF METAL-BINDING SITES ON METALLOPROTEINS

Authors
CHUNG KH HONG E DO Y MOON CH
Citation
Kh. Chung et al., UNUSUAL 6-COORDINATED AND 8-COORDINATED CADMIUM(II) MALONATE COMPLEX - RELEVANCE TO CD-113 NMR PROBE OF METAL-BINDING SITES ON METALLOPROTEINS, Journal of the Chemical Society, Chemical Communications, (22), 1995, pp. 2333-2334
Citations number
11
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
22
Year of publication
1995
Pages
2333 - 2334
Database
ISI
SICI code
0022-4936(1995):22<2333:U6A8CM>2.0.ZU;2-0
Abstract
The Cd-113 NMR spectrum of polymeric tetraaquobis(malonato)dicadmium(I I) 1 is characterized by two resonances and its crystal structure show s two cadmium sites in distinct chemical environments; the six- and ei ght-coordinate sites formed by oxygen donors are correlated with chemi cal shifts at delta 18 and -107, respectively.