REACTION KINETIC-STUDY ON ALTERNATING COPOLYMERIZATION OF VINYL MONOMERS COMPLEXED WITH ALKYLALUMINUM HALIDE

Authors
YABUUCHI H HIROOKA M KAETSU I
Citation
H. Yabuuchi et al., REACTION KINETIC-STUDY ON ALTERNATING COPOLYMERIZATION OF VINYL MONOMERS COMPLEXED WITH ALKYLALUMINUM HALIDE, Polymer Journal, 27(10), 1995, pp. 1021-1024
Citations number
11
Categorie Soggetti
Polymer Sciences
Journal title
Polymer Journal → ACNP
ISSN journal
00323896
Volume
27
Issue
10
Year of publication
1995
Pages
1021 - 1024
Database
ISI
SICI code
0032-3896(1995)27:10<1021:RKOACO>2.0.ZU;2-#
Abstract
The kinetic scheme of the alternating copolymerization of a donor mono mer and an acceptor monomer complexed with an alkylaluminum halide was studied to investigate the reaction mechanism. In the alternating cop olymerization of styrene (St) and methyl acrylate (MA) complexed with aluminum ethylsesquichloride (AlEt(1.5)Cl(1.5)), the kinetic data were expressed by the following equation (1). R(p)=k(0)[MA](1.0)[AlEt(1.5) Cl(1.5)](1.0)[St](0) together with the experimental observations the r eaction mechanism of the alternating copolymerization was discussed.