Al. Baner et al., ALTERNATIVE FATTY FOOD SIMULANTS FOR POLYMER MIGRATION TESTING - EXPERIMENTAL CONFIRMATION, Journal of polymer engineering, 15(1-2), 1996, pp. 161-180
A scheme is outlined for rapid and effective evaluation of food contac
t materials for compliance with food safety regulations. The scheme is
discussed in terms of migration into fatty foodstuffs at long-time ro
om temperature storage. Evaluation starts with compositional analysis
of the polymer using a rapid extraction test (24 h at 40 degrees C) to
extract all potential migratable substances from the polymer. Extract
ion test results using isooctane for polyolefins and ethanol for polar
polymers compared to global migration limits show the migration behav
ior of materials can be classified based on their thicknesses. Thin ma
terials with thickness less than or equal to 300 mu m seldom exceed mi
gration limits whereas thick (>300 mu m) often do, thus migration test
ing is most applicable for thick materials. The extraction test correl
ates with migration conditions up to and including sterilization hot f
ill (130 degrees C for 0.5 h). Comparison of global migration test dat
a into ethanol and olive oil for 32 commercial materials shows ethanol
can be used as an alternative simulant to oil. The extraction test re
sults represent an upper limit for global migration into oil from thin
materials.