SIZE-DEPENDENT STRATOSPHERIC DROPLET COMPOSITION IN LEE WAVE TEMPERATURE-FLUCTUATIONS AND THEIR POTENTIAL ROLE IN PSC FREEZING

Rapid temperature fluctuations are shown to cause liquid H2SO4/HNO3/H2 O stratospheric aerosols to depart considerably from thermodynamic equ ilibrium. While HNO3 uptake by larger droplets is diffusively hindered , small droplets can approach the composition of a pure binary HNO3/H2 O solution with up to 52 wt% HNO3, 48 wt% H2O and very small amounts o f H2SO4. The stoichiometry of these droplets is close to that of nitri c acid trihydrate (NAT) and freezing experiments suggest that this cou ld be a suitable pathway for the formation of frozen polar stratospher ic clouds (PSCs) of type-Ia.