The structure and properties of hexaferrites in the form of MFe(12)O(1
9) with M = Ba, Sr and Pb prepared by mechanical alloying and heat tre
atment have been studied. Coercivities of 6-7 kOe were measured for Ba
- and Sr-hexaferrite powders. The high values of coercivities have bee
n associated with small particle sizes (similar to 0.1 mu m) resulting
from the mechanical alloying and subsequent heat treatment. High-coer
civity anisotropic samples have been synthesized using hot-pressing, w
ith remanences of 70-75% of the saturation magnetisation being obtaine
d.