Wpjh. Jacobs et al., INELASTIC NEUTRON-SCATTERING STUDY OF NH4Y ZEOLITES, Journal of the Chemical Society. Faraday transactions, 90(8), 1994, pp. 1191-1196
Citations number
52
Categorie Soggetti
Chemistry Physical","Physics, Atomic, Molecular & Chemical
An inelastic neutron scattering study of NH4Y and CsNH4Y zeolites is p
resented from 2 to 350 meV (16-2800 cm-1). The spectra are interpreted
in terms of translational and librational motions of ammonium ions, a
mmonia and water molecules. For the hydrated samples the translational
modes of water species are observed at 12 meV and librational modes a
re found above ca. 50 meV. The translational and librational modes of
the ammonium ions also depend on the location of the cations. Ammonium
species give rise to (ion-lattice) translational modes at 10-15 meV a
nd at 15-25 meV for species localised in sodalite cages and supercages
, respectively. The corresponding librational modes are observed at ca
. 8 meV and in the region 3-6 meV, respectively. Strongly hindered lib
rations are observed at 50-70 meV and 30-50 meV, respectively, for the
ions in the two different cages. Low-frequency as well as high-freque
ncy librational modes of the ammonium species may occur caused by the
presence of different ammonium species. Differences in reorientational
motions are observed for hydrated zeolites and for reammoniated zeoli
tes. For the latter, a stronger interaction of the ammonium ions with
the zeolitic lattice is present and the low-frequency librational mode
s are shifted to higher energy-transfer values. When increasing the lo
ading with ammonia, librational and translational motions of ammonia s
pecies could be observed. Again, a heterogeneity in the reorientationa
l barriers is present, indicating the presence of different ammonia sp
ecies.