KSB2, A NEW STRUCTURE COMPOSED OF RIBBONS OF EDGE-SHARED 6-MEMBERED SB RINGS

Authors
REHR A GUERRA F PARKIN S HOPE H KAUZLARICH SM
Citation
A. Rehr et al., KSB2, A NEW STRUCTURE COMPOSED OF RIBBONS OF EDGE-SHARED 6-MEMBERED SB RINGS, Inorganic chemistry, 34(24), 1995, pp. 6218
Citations number
29
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
34
Issue
24
Year of publication
1995
Database
ISI
SICI code
0020-1669(1995)34:24<6218:KANSCO>2.0.ZU;2-7
Abstract
This note presents a unique structure which can be regarded as a missi ng link in the large number of polyanionic structures which are found in main-group compounds. The Sb atoms form a six-membered ring in the chair conformation that are connected to form a 1-dimensional ribbon. Electron counting and temperature dependent resistivity show that this compound can be classified as a Zintl compound.