SYNTHESIS AND SOLID-STATE STRUCTURE OF [HB(3,5-ME(2)PZ)(3)]IN(S-4)(3,5-ME(2)PZH) (PZ EQUALS PYRAZOLYL) - THE FIRST NEUTRAL INDIUM POLYSULFIDE COMPLEX

Authors
REGER DL COAN PS
Citation
Dl. Reger et Ps. Coan, SYNTHESIS AND SOLID-STATE STRUCTURE OF [HB(3,5-ME(2)PZ)(3)]IN(S-4)(3,5-ME(2)PZH) (PZ EQUALS PYRAZOLYL) - THE FIRST NEUTRAL INDIUM POLYSULFIDE COMPLEX, Inorganic chemistry, 34(24), 1995, pp. 6226
Citations number
18
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
34
Issue
24
Year of publication
1995
Database
ISI
SICI code
0020-1669(1995)34:24<6226:SASSO[>2.0.ZU;2-G
Abstract
The reaction of [HB(3,5-Me(2)pz)(3)]InCl2 (pz = pyrazolyl) with K2S5 y ields the first neutral group 13 metal polysulfide complex [HB(3,5-Me( 2)pz)(3)]In(S-4)(3,5-Me(2)-pzH). The structure of this complex has a d istorted octahedral geometry about indium. The InS4 ring is arranged i n a half-chair configuration.