AL-27 AND C-13 NMR RELAXATION STUDIES OF AMINOALANES

Authors
WATKINS CL KRANNICH LK SCHAUER SJ
Citation
Cl. Watkins et al., AL-27 AND C-13 NMR RELAXATION STUDIES OF AMINOALANES, Inorganic chemistry, 34(24), 1995, pp. 6228
Citations number
33
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
34
Issue
24
Year of publication
1995
Database
ISI
SICI code
0020-1669(1995)34:24<6228:AACNRS>2.0.ZU;2-D
Abstract
Al-27 and C-13 NMR relaxation data are reported for the aminoalane ser ies [R(2)AlNMe(2)](2), and Al-27 relaxation data, for the series [Me(2 )AlR'](2) and Me(3)Al . R'H. A linear correlation exists between the A l-27 NMR half-height line width and molar volume for [Me(2)AlR'](2) an d Me(3)Al . R'H, where R'H represents 12 secondary amines. Variable te mperature Al-27 and C-13 NMR relaxation data suggest a single effectiv e correlation time in the [R(2)AlNMe(2)](2) series.