TRICARBONYL ETA(6)-TRIMETHYLPHENYLSILANE)-MOLYBDENUM

Citation
Ec. Alyea et al., TRICARBONYL ETA(6)-TRIMETHYLPHENYLSILANE)-MOLYBDENUM, Acta crystallographica. Section C, Crystal structure communications, 50, 1994, pp. 491-493
Citations number
17
Categorie Soggetti
Crystallography
ISSN journal
01082701
Volume
50
Year of publication
1994
Part
4
Pages
491 - 493
Database
ISI
SICI code
0108-2701(1994)50:<491:TE>2.0.ZU;2-R
Abstract
The Mo atom in tricarbonyl(eta6-trimethylphenylsilane)molybdenum, [Mo( C9H14Si)(CO)3] (1), is situated 1.908 (3) angstrom above the centre of the arene ring with Mo-C distances in the range 2.351 (5)-2.388 (5) a ngstrom. The carbonyl groups are staggered (26-degrees from a fully ec lipsed conformation) with respect to the arene-ring C atoms.