OPENTADIENYL)BIS(TRIPHENYLPHOS-PHINE)RUTHENIUM(II)

Authors
KHAN MMT BHADBHADE MM SIDDIQUI MRH VENKATASUBRAMANIAN K TIKHONOVA JA
Citation
Mmt. Khan et al., OPENTADIENYL)BIS(TRIPHENYLPHOS-PHINE)RUTHENIUM(II), Acta crystallographica. Section C, Crystal structure communications, 50, 1994, pp. 502-504
Citations number
13
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
50
Year of publication
1994
Part
4
Pages
502 - 504
Database
ISI
SICI code
0108-2701(1994)50:<502:O>2.0.ZU;2-B
Abstract
The molecule [RuN3(C5H5){P(C6H5)3}2] has a typical three-legged-piano- stool geometry; Ru-Cp0 (where Cp0 is the centre of the ring) is 1.843 (3) angstrom, the three legs are 2.3293 (5) and 2.3304 (5) (Ru-P) and 2.135 (3) angstrom (Ru-N) in length while the angles are P-Ru-P 105.22 (2), P-Ru-N 85.39 (6) and 86.65 (5)-degrees. The azide group is almos t linear [N-N-N 175.2 (3)-degrees] and is coordinated to Ru with an Ru -N-N angle of 124.5 (2)-degrees; there is a small difference between t he N-N distances [1.186 (3) and 1.164 (3) angstrom], the longer being adjacent to the Ru atom.