A NEW ORTHORHOMBIC CRYSTAL FORM OF HENYLPHOSPHINOMETHYL)-1,3-DIOXOLANE-P,P']PLATINUM, [((R,R)-DIOP)PTCL2]

Citation
C. Ganter et al., A NEW ORTHORHOMBIC CRYSTAL FORM OF HENYLPHOSPHINOMETHYL)-1,3-DIOXOLANE-P,P']PLATINUM, [((R,R)-DIOP)PTCL2], Acta crystallographica. Section C, Crystal structure communications, 50, 1994, pp. 507-510
Citations number
6
Categorie Soggetti
Crystallography
ISSN journal
01082701
Volume
50
Year of publication
1994
Part
4
Pages
507 - 510
Database
ISI
SICI code
0108-2701(1994)50:<507:ANOCFO>2.0.ZU;2-3
Abstract
In the orthorhombic form of the title compound, [PtCl2(C31H32O2P2)], t he geometry at Pt is approximately square planar and the molecular con formation observed is qualitatively similar to that of one of the two independent molecules in a triclinic polymorph determined previously. The crystal and molecular structures are pseudo-isomorphous with those of [{(S,S)-diop}PtMeCl].