PENTAAZAHEXADECANE-KAPPA(5)N2,5,8,12,15]COPPER(II) DIPERCHLORATE

Authors
TAHIROV TH LU TH LIU YL CHUNG CS
Citation
Th. Tahirov et al., PENTAAZAHEXADECANE-KAPPA(5)N2,5,8,12,15]COPPER(II) DIPERCHLORATE, Acta crystallographica. Section C, Crystal structure communications, 50, 1994, pp. 514-516
Citations number
9
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
50
Year of publication
1994
Part
4
Pages
514 - 516
Database
ISI
SICI code
0108-2701(1994)50:<514:PD>2.0.ZU;2-H
Abstract
The Cu(II) atom in the title complex, [Cu(C11H29N5)]-(ClO4)3, is five- coordinate and is in a distorted trigonal-bipyramidal conformation. Th e longer Cu(equatorial)-N bond distances compared to the Cu(axial)-N d istances indicate the steric influence of the two N-methyl groups. The ligand is in its stable conformation with the three five-membered che late rings in stable skew forms and the six-membered ring in a stable chair form.