D. Gersappe et Ac. Balazs, RANDOM COPOLYMERS AS EFFECTIVE COMPATIBILIZING AGENTS, Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics, 52(5), 1995, pp. 5061-5064
We introduce a mean field model that allows us to determine the interf
acial behavior of AB random copolymers. Through this model, we calcula
te the reduction in interfacial tension gamma that occurs when the ran
dom copolymers localize at the interface between immiscible homopolyme
rs A and B. We also isolate the conditions under which the random copo
lymers are most efficient at reducing gamma and therefore act as effic
ient compatibilizers. The calculations are useful in designing low-cos
t copolymer additives that significantly improve the properties of pol
ymer blends.