Wg. Huang et Db. Hibbert, MODELING OF METAL ELECTRODEPOSITS - ANALYTICAL SOLUTIONS, Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics, 52(5), 1995, pp. 5065-5069
From a model of metal electrodeposition, expressions of the concentrat
ion and current for diffusion, convection, and voltage in one dimensio
n are derived. Our models are exact solutions of differential equation
s. The effect of dissolution of the anode, direction and speed of conv
ection, and voltage on the concentration, current, and growth speed ar
e determined. The origin of currents that are independent of the appli
ed potential is explained.