MAIN-GROUP COMPLEXES OF AMINOPHENOL - THE X-RAY STRUCTURE OF SN[C6H4(NH2)(O)]2CL2

Authors
LEWIS DA WILLIAMS DJ SLAWIN AM WOOLLINS JD
Citation
Da. Lewis et al., MAIN-GROUP COMPLEXES OF AMINOPHENOL - THE X-RAY STRUCTURE OF SN[C6H4(NH2)(O)]2CL2, Polyhedron, 15(3), 1996, pp. 555-558
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
15
Issue
3
Year of publication
1996
Pages
555 - 558
Database
ISI
SICI code
0277-5387(1996)15:3<555:MCOA-T>2.0.ZU;2-Q
Abstract
Deprotonation of aminophenol (ampH(3)) followed by reaction with SnCl4 . 5H(2)O or Al(OPri)(3) gives Sn(ampH(2))(2)Cl-2 (1) and Al(ampH(2))( 3) (2). The X-ray structure of 1 reveals cis, cis, trans coordination, although in solution the Sn-119 NMR indicates a mixture of isomers.