INVESTIGATION OF THE PROCESS OF DIAMOND FORMATION FROM SIC UNDER HIGH-PRESSURE AND HIGH-TEMPERATURE

Authors
Citation
L. Gou et al., INVESTIGATION OF THE PROCESS OF DIAMOND FORMATION FROM SIC UNDER HIGH-PRESSURE AND HIGH-TEMPERATURE, Journal of Materials Science, 30(22), 1995, pp. 5687-5690
Citations number
10
Categorie Soggetti
Material Science
ISSN journal
00222461
Volume
30
Issue
22
Year of publication
1995
Pages
5687 - 5690
Database
ISI
SICI code
0022-2461(1995)30:22<5687:IOTPOD>2.0.ZU;2-I
Abstract
SiC powder or graphite in contact with cobalt, nickel or a Ni70Mn25Co5 alloy was treated at high pressure and high temperature in stable reg ion of diamond. It was found that Ni70Mn25Co5 alloy is more effective in the process of diamond formation from SiC than the others, but the difference was not apparent when graphite was used instead of SIG. Usi ng the Ni70Mn25Co5 alloy, diamond formed rapidly with the decompositio n of SIC at a pressure of 5.4-6.0 GPa and temperature 1350-1570 degree s C, and the growth tended to stagnate after 6 min, when SiC was compl etely exhausted. X-ray diffraction showed that the relative intensity of the diffraction lines of diamond and graphite was nearly constant i n the samples synthesized under the same conditions for 2, 4 and 6 min . The results suggest that diamond and graphite may be formed directly and respectively from separated carbon atoms in a short time.