L. Gou et al., INVESTIGATION OF THE PROCESS OF DIAMOND FORMATION FROM SIC UNDER HIGH-PRESSURE AND HIGH-TEMPERATURE, Journal of Materials Science, 30(22), 1995, pp. 5687-5690
SiC powder or graphite in contact with cobalt, nickel or a Ni70Mn25Co5
alloy was treated at high pressure and high temperature in stable reg
ion of diamond. It was found that Ni70Mn25Co5 alloy is more effective
in the process of diamond formation from SiC than the others, but the
difference was not apparent when graphite was used instead of SIG. Usi
ng the Ni70Mn25Co5 alloy, diamond formed rapidly with the decompositio
n of SIC at a pressure of 5.4-6.0 GPa and temperature 1350-1570 degree
s C, and the growth tended to stagnate after 6 min, when SiC was compl
etely exhausted. X-ray diffraction showed that the relative intensity
of the diffraction lines of diamond and graphite was nearly constant i
n the samples synthesized under the same conditions for 2, 4 and 6 min
. The results suggest that diamond and graphite may be formed directly
and respectively from separated carbon atoms in a short time.