MOLYBDENUM(VI) CATALYSIS OF PERBORATE OR HYDROGEN-PEROXIDE OXIDATION OF IODIDE-ION

Authors
KARUNAKARAN C MUTHUKUMARAN B
Citation
C. Karunakaran et B. Muthukumaran, MOLYBDENUM(VI) CATALYSIS OF PERBORATE OR HYDROGEN-PEROXIDE OXIDATION OF IODIDE-ION, Transition metal chemistry, 20(5), 1995, pp. 460-462
Citations number
9
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Transition metal chemistry
ISSN journal
03404285 → ACNP
Volume
20
Issue
5
Year of publication
1995
Pages
460 - 462
Database
ISI
SICI code
0340-4285(1995)20:5<460:MCOPOH>2.0.ZU;2-P
Abstract
Perborate in aqueous solution generates H2O2; in its presence the moly bdenum(VI) catalysed oxidation of iodide ion is first order with respe ct to the oxidant and catalyst, and is independent of [I-] and [H+]. K inetic studies point to peroxymolybdenum(VI) species as the oxidizing species.