REACTIONS OF [(CP)2TI(NCS)2] AS A POTENTIAL METALLOLIGAND - SYNTHESISAND PHYSICOCHEMICAL INVESTIGATIONS OF NOVEL HETEROBIMETALLIC COMPLEXES

Authors
SIDDIQI ZA KHAN AA
Citation
Za. Siddiqi et Aa. Khan, REACTIONS OF [(CP)2TI(NCS)2] AS A POTENTIAL METALLOLIGAND - SYNTHESISAND PHYSICOCHEMICAL INVESTIGATIONS OF NOVEL HETEROBIMETALLIC COMPLEXES, Transition metal chemistry, 20(5), 1995, pp. 469-471
Citations number
18
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Transition metal chemistry
ISSN journal
03404285 → ACNP
Volume
20
Issue
5
Year of publication
1995
Pages
469 - 471
Database
ISI
SICI code
0340-4285(1995)20:5<469:RO[AAP>2.0.ZU;2-Y
Abstract
Bis(cyclopentadienyl)titanium(IV) diisothiocyanate [(Cp)(2)Ti(NCS)(2)] reacts with MCl(2) (M = Cu, pd or Pt), [CuCl(PPh(3))(3)], [RuCl2(PPh( 3))(3)] and [RuCl2(DMSO)(4)] (DMSO = dimethylsulphoxide) giving solid compounds of stochiometry [(Cp)(2)Ti(mu-NCS)(2)MCl(2)] (M = Cu, Pd or Pt), [(Cp)(2)Ti(mu-NCS)(2)CuCl(PPh(3))], [(Cp)(2)Ti(mu-NCS)(2)RuCl(PPh (3))(2)]Cl and [(Cp)(2)Ti(mu-NCS)(2)RuCl2(DMSO)(2)]. These products ha ve been characterized by physico-chemical and spectroscopic methods.