MAGNETIC AND SPECTROSCOPIC PROPERTIES OF COPPER(II) COMPLEXES WITH 1-SALICOYL-4-PHENYLTHIOSEMICARBAZIDE

Authors
AKINCHAN NT WEST DX YANG YH SALBERG MM KLEIN TL
Citation
Nt. Akinchan et al., MAGNETIC AND SPECTROSCOPIC PROPERTIES OF COPPER(II) COMPLEXES WITH 1-SALICOYL-4-PHENYLTHIOSEMICARBAZIDE, Transition metal chemistry, 20(5), 1995, pp. 481-484
Citations number
50
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Transition metal chemistry
ISSN journal
03404285 → ACNP
Volume
20
Issue
5
Year of publication
1995
Pages
481 - 484
Database
ISI
SICI code
0340-4285(1995)20:5<481:MASPOC>2.0.ZU;2-Z
Abstract
Cu-II complexes of 1-salicoyl-4-phenylthiosemicarbazide (SPT) have bee n synthesized and characterized by means of elemental analysis, magnet ic measurements, and i.r. and e.p.r. spectroscopic methods; H-1- and C -13-n.m.r, and mass spectral data on the thiosemicarbazide are also re ported. A paramagnetic complex mu(eff) = 1.298 B.M., is formed with co pper(II) sulphate; the low magnetic moment and the e.p.r. spectral dat a suggest a binuclear species. A diamagnetic complex due to a strong C u-Cu interaction has been isolated with copper(II) chloride.