STEREOSTRUCTURE OF RIMOCIDIN

Authors
SOWINSKI P PAWLAK J BOROWSKI E GARIBOLDI P
Citation
P. Sowinski et al., STEREOSTRUCTURE OF RIMOCIDIN, Journal of antibiotics, 48(11), 1995, pp. 1288-1291
Citations number
7
Categorie Soggetti
Pharmacology & Pharmacy",Immunology,"Biothechnology & Applied Migrobiology
Journal title
Journal of antibiotics → ACNP
ISSN journal
00218820
Volume
48
Issue
11
Year of publication
1995
Pages
1288 - 1291
Database
ISI
SICI code
0021-8820(1995)48:11<1288:SOR>2.0.ZU;2-E
Abstract
NMR studies of rimocidin, consisting of DQF-COSY, ROESY, HSQC, HMBC an d 1D-TOCSY experiments, resulted in the assignment of the absolute con figuration of the rimocidin chiral centers as 2S, 3R, 9S, 11R, 13S, 14 R, 15S, 17R and 27R. The geometry of tetraene chromophore was found to be all-trans.