The growth and decay of a weak discontinuity headed by a singular surf
ace of arbitrary shape in three dimensions is investigated in a chemic
ally reacting atmosphere, in the absence of dissipative mechanisms suc
h as viscosity, diffusion and heat conduction. The combined effects of
the disequilibrium due to the chemical reaction and a wave front curv
ature on the propagation of discontinuities have been examined and dis
cussed. It has been observed that the chemical disequilibrium, with it
s Arrhenius rate dependence, causes the compression wave to steepen mo
re swiftly that it does in an inert atmosphere. The critical values of
the initial discontinuity, and time for shock formation, in cases of
diverging and converging waves, have been determined.