THE REACTION OF AMMONIA WITH NITROGEN-DIOXIDE IN A FLOW REACTOR - IMPLICATIONS FOR THE NH2+NO2 REACTION

The NH3/NO2 system has been investigated experimentally in an isotherm al flow reactor in the temperature range 850-1350 X. The experimental data were interpreted in terms of a detailed reaction mechanism. The f low reactor results, supported by a theoretical analysis of the NH2-NO 2 complex, suggest that the NH2 + NO2 reaction has two major product c hannels, both proceeding without activation barriers: (R20) NH2 revers ible arrow N2O + H2O (R20) NH2 reversible arrow H2NO + NO Our findings indicate that the N2O + H2O channel is dominant at low temperatures w hile H2NO + NO dominates at high temperatures. The rate constant for r eaction (R21) is estimated to be 3.5 . 10(12) cm(3)/mol-s in the tempe rature range studied with an uncertainty of a factor of 3. (C) 1995 Jo hn Wiley & Sons, Inc.