ADSORPTION OF MOLECULAR NITROGEN ON RHODIUM SUPPORTED ON DEALUMINATEDZEOLITE-Y - THE FORMATION OF WELL-DEFINED SURFACE DINITROGEN COMPLEXES

Authors
MIESSNER H
Citation
H. Miessner, ADSORPTION OF MOLECULAR NITROGEN ON RHODIUM SUPPORTED ON DEALUMINATEDZEOLITE-Y - THE FORMATION OF WELL-DEFINED SURFACE DINITROGEN COMPLEXES, Journal of the Chemical Society, Chemical Communications, (8), 1994, pp. 927-928
Citations number
23
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
8
Year of publication
1994
Pages
927 - 928
Database
ISI
SICI code
0022-4936(1994):8<927:AOMNOR>2.0.ZU;2-Y
Abstract
The surface complexes Rh-I(CO)(N-2)(+) with nu(CO) 2062 cm(-1) and V(N -2) 2252 cm(-1) and Rh-l(N-2)(2)(+) nu(N-2) 2244 + 2218 cm(-1), which are stable in flowing nitrogen up to 250 degrees C, have been synthesi sed from Rh-I(CO)(2)(+) on highly dealuminated zeolite Y (DAY, US-Ex).