(2-HYDROXYPHENYLMETHYLENE)BIS(PHOSPHINE OXIDES) - A FACILE REARRANGEMENT INTO 2-(PHOSPHINYLMETHYL)PHENYL PHOSPHINATES

Authors
BOVIN AN YARKEVICH AN KHARITONOV AV TSVETKOV EN
Citation
An. Bovin et al., (2-HYDROXYPHENYLMETHYLENE)BIS(PHOSPHINE OXIDES) - A FACILE REARRANGEMENT INTO 2-(PHOSPHINYLMETHYL)PHENYL PHOSPHINATES, Journal of the Chemical Society, Chemical Communications, (8), 1994, pp. 973-974
Citations number
20
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
8
Year of publication
1994
Pages
973 - 974
Database
ISI
SICI code
0022-4936(1994):8<973:(O-AFR>2.0.ZU;2-V
Abstract
(2-Hydroxyphenylmethylene)bis(phosphine oxides)3 prepared from 2-(diph enylphosphinylmethyl)phenyl phosphinates 2 by oxygen-to-carbon 1,4-pho sphinyl migration easily rearrange back into a mixture of 2-(phosphiny lmethyl)phenyl phosphinates 2 and 4 under basic conditions or upon hea ting.