PHOTOSENSITIZED OXIDATION OF FURANS .19. STEREOSELECTIVE SYNTHESIS OFFUNCTIONALIZED METHYL CIS 3-AROYL-2,3-EPOXYPROPANOATES VIA ARYL-5-HYDROPEROXY-2,2-DIMETHOXY-2,5-DIHYDROFURANS

Authors
IESCE MR CERMOLA F GUITTO A SCARPATI R GRAZIANO ML
Citation
Mr. Iesce et al., PHOTOSENSITIZED OXIDATION OF FURANS .19. STEREOSELECTIVE SYNTHESIS OFFUNCTIONALIZED METHYL CIS 3-AROYL-2,3-EPOXYPROPANOATES VIA ARYL-5-HYDROPEROXY-2,2-DIMETHOXY-2,5-DIHYDROFURANS, Synlett, (11), 1995, pp. 1161
Citations number
32
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synlett → ACNP
ISSN journal
09365214
Issue
11
Year of publication
1995
Database
ISI
SICI code
0936-5214(1995):11<1161:POOF.S>2.0.ZU;2-X
Abstract
Functionalized methyl cb 3-aroyl-2,3-epoxypropanoates 1 are synthesize d by singlet oxygen oxygenation of 5-aryl-2-methoxyfurans 2 in methano l and by base treatment of the resulting crude dihydrofurans 3. Screen ing experiments revealed that the reaction occurs efficiently only whe n an electron-withdrawing group is bound at C-4 of 3.