REDUCTION OF PHOSPHINE OXIDES, A MILD AND PRACTICAL SYNTHESIS OF SECONDARY P-ETHYNYLPHOSPHINES

Authors
PILARD JF BABA G GAUMONT AC DENIS JM
Citation
Jf. Pilard et al., REDUCTION OF PHOSPHINE OXIDES, A MILD AND PRACTICAL SYNTHESIS OF SECONDARY P-ETHYNYLPHOSPHINES, Synlett, (11), 1995, pp. 1168
Citations number
23
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synlett → ACNP
ISSN journal
09365214
Issue
11
Year of publication
1995
Database
ISI
SICI code
0936-5214(1995):11<1168:ROPOAM>2.0.ZU;2-3
Abstract
Secondary P-ethynylphosphines bearing non-uncumbered substituants are synthesized by reduction of the easily available oxide precursors with phenylsilane for the P-alkyl derivatives and with a complex reducing agent (PhSiH(3)-PhSiCl(3)) or pure PhSi(H)Cl-2 for the P-phenyl deriva tives.