STABILITY ENHANCEMENT OF HEAVY-METAL-MACROCYCLE COMPLEXES VIA PENDANTAMIDE COORDINATION

Authors
CARLTON L HANCOCK RD MAUMELA H WAINWRIGHT KP
Citation
L. Carlton et al., STABILITY ENHANCEMENT OF HEAVY-METAL-MACROCYCLE COMPLEXES VIA PENDANTAMIDE COORDINATION, Journal of the Chemical Society, Chemical Communications, (8), 1994, pp. 1007-1008
Citations number
6
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
8
Year of publication
1994
Pages
1007 - 1008
Database
ISI
SICI code
0022-4936(1994):8<1007:SEOHCV>2.0.ZU;2-9
Abstract
Formation of the pendant-arm macrocyclic ligand is(carbamoylmethyl)-1, 4,7,10-tetraazacyclododecane L and subsequent generation of its cadmiu m(ir) complex indicates very significant stabilisation of the complex, compared to that observed for related macrocyclic cadmium(ri) complex es, which either lack pendant donors altogether, or have other types o f neutral oxygen donors attached to the macrocycle, and compared to co mplexes of L with lighter metal ions.