MODEL FOR THE DESCRIPTION OF THE DYNAMIC AND ELECTROOPTIC PROPERTIES OF HYDROGEN-BONDS

A semiempirical one-parameter model is proposed to describe the dynami c and electrooptic properties of hydrogen bonds. The model allows one to determine all parameters that are necessary for calculating the vib rational spectra of complexes using the strength of intermolecular bin ding. The experimental IR spectra of some hydrogen-bonded systems are compared to the corresponding spectra calculated by this model. it is shown that the model is applicable to calculating the first-to-third o rder vibrations of any hydrogen-bonded complex.